Pyrrole–aryl derivatives are important due to their unique biological activities in medicinal chemistry. We now report a new oxidative biaryl coupling for pyrroles and indoles toward various arenes using a hypervalent iodine reagent and an appropriate stabilizer for pyrrolyl iodonium intermediates. The reactions readily provide a variety of desired coupling products in good yields.
K. Morimoto, Y. Ohnishi, D. Koseki, A. Nakamura, T. Dohi and Y. Kita, Org. Biomol. Chem., 2016, 14, 8947 DOI: 10.1039/C6OB01764A
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