Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 22nd May 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 32, 2016
Previous Article Next Article

Synthesis of the 2-formylpyrrole spiroketal pollenopyrroside A and structural elucidation of xylapyrroside A, shensongine A and capparisine B

Author affiliations

Abstract

A convergent synthesis of the 2-formyl pyrrole spiroketal pollenopyrroside A is reported. The key step involves a Maillard-type condensation of an amine derived from deoxy-D-ribose with a dihydropyranone to furnish the 2-formylpyrrole ring system. Spectroscopic and physical data of 9-epi-pollenopyrroside A are also provided, elucidating the structures of the previously isolated 2-formylpyrrole spiroketals capparisine B, shensongine A and xylapyrroside A.

Graphical abstract: Synthesis of the 2-formylpyrrole spiroketal pollenopyrroside A and structural elucidation of xylapyrroside A, shensongine A and capparisine B

Back to tab navigation

Supplementary files

Publication details

The article was received on 24 Jun 2016, accepted on 20 Jul 2016 and first published on 20 Jul 2016


Article type: Paper
DOI: 10.1039/C6OB01361A
Org. Biomol. Chem., 2016,14, 7659-7664

  •   Request permissions

    Synthesis of the 2-formylpyrrole spiroketal pollenopyrroside A and structural elucidation of xylapyrroside A, shensongine A and capparisine B

    J. M. Wood, D. P. Furkert and M. A. Brimble, Org. Biomol. Chem., 2016, 14, 7659
    DOI: 10.1039/C6OB01361A

Search articles by author

Spotlight

Advertisements