Issue 24, 2016
From the journal:

Organic & Biomolecular Chemistry

Copper-catalyzed electrophilic amination using N-methoxyamines†

Yutaro Fukami,a   Takamasa Wada,a   Tatsuhiko Meguro,a   Noritaka Chidaa  and  Takaaki Sato*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1, Hiyoshi, Kohoku-ku, Yokohama 223-8522, Japan
E-mail: takaakis@applc.keio.ac.jp

Abstract

Copper-catalyzed electrophilic amination of a triarylboroxin using an N-methoxyamine to give quick access to a variety of anilines was reported. The reaction was especially useful for syntheses of functionalized anilines when combined with our previously reported nucleophilic addition to N-methoxyamides.

Graphical abstract: Copper-catalyzed electrophilic amination using N-methoxyamines

  • This article is part of the themed collection: New Talent
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Article information

DOI
https://doi.org/10.1039/C5OB02167G
Article type
Communication
Submitted
20 Oct 2015
Accepted
28 Oct 2015
First published
29 Oct 2015

Org. Biomol. Chem., 2016,14, 5486-5489

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Copper-catalyzed electrophilic amination using N-methoxyamines

Y. Fukami, T. Wada, T. Meguro, N. Chida and T. Sato, Org. Biomol. Chem., 2016, 14, 5486 DOI: 10.1039/C5OB02167G

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