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Issue 24, 2016
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anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(iii) reagents

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Abstract

anti-Selective aminofluorination of alkenes with amidines was enabled by hypervalent iodine(III) reagents, affording 4-fluoroalkyl-2-imidazolines. Further reductive ring-opening of the 2-imidazoline moiety could deliver highly functionalized 3-fluoropropane-1,2-diamine derivatives.

Graphical abstract: anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(iii) reagents

  • This article is part of the themed collection: New Talent
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Supplementary files

Article information


Submitted
05 Sep 2015
Accepted
24 Sep 2015
First published
24 Sep 2015

Org. Biomol. Chem., 2016,14, 5481-5485
Article type
Communication

anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(III) reagents

H. Chen, A. Kaga and S. Chiba, Org. Biomol. Chem., 2016, 14, 5481
DOI: 10.1039/C5OB01854D

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