Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 12, 2016
Previous Article Next Article

Tuning and enhancement of the Mizoroki–Heck reaction using polarized Pd nanocomposite carbon aerogels

Author affiliations

Abstract

The application of a positive electric field on a Pd(0)–carbon aerogel nanocomposite enhances the reaction rate of the Mizoroki–Heck reaction. By contrast, when a negative potential is employed the reaction is inhibited. On the other hand, chronoamperometry measurements have revealed the polarizing current intensity as an indirect measure of the reaction evolution. The cationic nature of the reaction intermediates was unambiguously confirmed and a polar mechanism has been finally proposed.

Graphical abstract: Tuning and enhancement of the Mizoroki–Heck reaction using polarized Pd nanocomposite carbon aerogels

Back to tab navigation

Supplementary files

Article information


Submitted
21 Jul 2016
Accepted
14 Oct 2016
First published
17 Oct 2016

This article is Open Access

New J. Chem., 2016,40, 10208-10212
Article type
Paper

Tuning and enhancement of the Mizoroki–Heck reaction using polarized Pd nanocomposite carbon aerogels

L. Martín, E. Molins and A. Vallribera, New J. Chem., 2016, 40, 10208
DOI: 10.1039/C6NJ02279K

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.

Reproduced material should be attributed as follows:

  • For reproduction of material from NJC:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
  • For reproduction of material from PCCP:
    [Original citation] - Published by the PCCP Owner Societies.
  • For reproduction of material from PPS:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
  • For reproduction of material from all other RSC journals:
    [Original citation] - Published by The Royal Society of Chemistry.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.


Social activity

Search articles by author

Spotlight

Advertisements