Issue 19, 2016

CO2-Catalysed aldol condensation of 5-hydroxymethylfurfural and acetone to a jet fuel precursor

Abstract

CO2 can act as a catalyst for the production of bio-jet fuel precursors through aldol condensation. CO2-Catalysed aldol condensation of HMF with acetone gives a >95% yield of [4-(5-hydroxymethyl-2-furyl)-3-butenone] mono-aldol condensate, while direct conversion of glucose to the same mono-aldol condensate gave a yield of 11%.

Graphical abstract: CO2-Catalysed aldol condensation of 5-hydroxymethylfurfural and acetone to a jet fuel precursor

Supplementary files

Article information

Article type
Communication
Submitted
21 Jun 2016
Accepted
08 Aug 2016
First published
09 Aug 2016

Green Chem., 2016,18, 5118-5121

Author version available

CO2-Catalysed aldol condensation of 5-hydroxymethylfurfural and acetone to a jet fuel precursor

R. Lee, J. R. Vanderveen, P. Champagne and P. G. Jessop, Green Chem., 2016, 18, 5118 DOI: 10.1039/C6GC01697A

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