Issue 10, 2016
From the journal:

Green Chemistry

Nickel-catalyzed hydrocarboxylation of alkynes with formic acid†

Jing Hou,a   Ming-Lei Yuan,a   Jian-Hua Xiea  and  Qi-Lin Zhou*ab  

* Corresponding authors

a State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

b Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300071, China
E-mail: qlzhou@nankai.edu.cn

Abstract

A protocol for nickel-catalyzed hydrocarboxylation of alkynes with formic acid was developed. The protocol allowed for highly efficient synthesis of acrylic acid with a TON of up to 7700.

Graphical abstract: Nickel-catalyzed hydrocarboxylation of alkynes with formic acid

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Article information

DOI
https://doi.org/10.1039/C6GC00549G
Article type
Communication
Submitted
26 Feb 2016
Accepted
21 Apr 2016
First published
21 Apr 2016

Green Chem., 2016,18, 2981-2984

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Nickel-catalyzed hydrocarboxylation of alkynes with formic acid

J. Hou, M. Yuan, J. Xie and Q. Zhou, Green Chem., 2016, 18, 2981 DOI: 10.1039/C6GC00549G

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