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Issue 9, 2016
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Production of C4 and C5 alcohols from biomass-derived materials

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Abstract

C4 and C5 diols and alcohols are important commodity chemicals mainly used as monomers in the production of polyesters, polyurethanes and polyethers. C4 and C5, on the other hand, can be used in the fuel industry for the preparation of additives to boost the gasoline octane number. The present critical review covers those reports describing the obtainment of these diols and alcohols from precursors derived from biomass. Emphasis is made on the description of the catalysts required for these transformations and on common traits referring to the bifunctionality combining hydrogenation activity and acidity and on the mechanistic proposals. The need for finding a suitable replacement for noble metals on the composition of these catalysts has been remarked throughout the review.

Graphical abstract: Production of C4 and C5 alcohols from biomass-derived materials

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Publication details

The article was received on 08 Feb 2016, accepted on 22 Mar 2016 and first published on 22 Mar 2016


Article type: Critical Review
DOI: 10.1039/C6GC00377J
Green Chem., 2016,18, 2579-2597

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    Production of C4 and C5 alcohols from biomass-derived materials

    D. Sun, S. Sato, W. Ueda, A. Primo, H. Garcia and A. Corma, Green Chem., 2016, 18, 2579
    DOI: 10.1039/C6GC00377J

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