Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling

Audrey Beillard; Xavier Bantreil; Thomas-Xavier Métro; Jean Martinez; Frédéric Lamaty

doi:10.1039/C6DT03564G

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Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)₂]Y (Y = BF₄, PF₆) complexes by ball-milling†

Audrey Beillard,^a Xavier Bantreil,

*^a Thomas-Xavier Métro,

*^a Jean Martinez^a and Frédéric Lamaty*^a

Author affiliations

* Corresponding authors

^a Institut des Biomolécules Max Mousseron (IBMM), UMR 5247, Université de Montpellier, CNRS, ENSCM, Université de Montpellier, Campus Triolet, Place Eugène Bataillon, 34095 Montpellier cedex 5, France
E-mail: xavier.bantreil@umontpellier.fr, thomas-xavier.metro@umontpellier.fr, frederic.lamaty@umontpellier.fr

Abstract

A user-friendly and general mechanochemical method was developed to access rarely described NHC (N-heterocyclic carbene) silver(I) complexes featuring N,N-diarylimidazol(idin)ene ligands and non-coordinating tetrafluoroborate or hexafluorophosphate counter anions. Comparison with syntheses in solution clearly demonstrated the superiority of the ball-milling conditions.

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Article information

DOI: https://doi.org/10.1039/C6DT03564G
Article type: Paper
Submitted: 13 Sep 2016
Accepted: 12 Oct 2016
First published: 24 Oct 2016

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Dalton Trans., 2016,45, 17859-17866

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Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)₂]Y (Y = BF₄, PF₆) complexes by ball-milling

A. Beillard, X. Bantreil, T. Métro, J. Martinez and F. Lamaty, Dalton Trans., 2016, 45, 17859 DOI: 10.1039/C6DT03564G

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Dalton Transactions