Oxygen reduction reaction catalyzed by nickel complexes based on thiophosphorylated calix[4]resorcinols and immobilized in the membrane electrode assembly of fuel cells

M. K. Kadirov; I. R. Knyazeva; I. R. Nizameev; R. A. Safiullin; V. I. Matveeva; K. V. Kholin; V. V. Khrizanforova; T. I. Ismaev; A. R. Burilov; Yu. H. Budnikova; O. G. Sinyashin

doi:10.1039/C6DT02881K

Oxygen reduction reaction catalyzed by nickel complexes based on thiophosphorylated calix[4]resorcinols and immobilized in the membrane electrode assembly of fuel cells†

M. K. Kadirov,*^ab I. R. Knyazeva,^a I. R. Nizameev,^ac R. A. Safiullin,^b V. I. Matveeva,^a K. V. Kholin,^ab V. V. Khrizanforova,^a T. I. Ismaev,^b A. R. Burilov,^a Yu. H. Budnikova^a and O. G. Sinyashin^a

Author affiliations

* Corresponding authors

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, 8, Akad. Arbuzov str., Kazan 420088, Russia
E-mail: kadirovmarsil@gmail.com

^b Kazan National Research Technological University, 68, K. Marx str., Kazan 420015, Russia

^c Kazan National Research Technical University, 10, K. Marx str., Kazan 420111, Russia

Abstract

The catalytic activity of the nickel complexes of thiophosphorylated calix[4]resorcinols for oxygen reduction in a polymer electrolyte membrane fuel cell (PEMFC) has been studied. The conformation of the macrocyclic ligand determines the morphology and catalytic properties of the resulting organometallic species.

Dalton Transactions

Oxygen reduction reaction catalyzed by nickel complexes based on thiophosphorylated calix[4]resorcinols and immobilized in the membrane electrode assembly of fuel cells†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Oxygen reduction reaction catalyzed by nickel complexes based on thiophosphorylated calix[4]resorcinols and immobilized in the membrane electrode assembly of fuel cells

Social activity

Search articles by author

Spotlight

Advertisements