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Issue 32, 2016
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New N^C^N-coordinated Pd(ii) and Pt(ii) complexes of a tridentate N-heterocyclic carbene ligand featuring a 6-membered central ring: synthesis, structures and luminescence

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Abstract

We describe Pd(II) and Pt(II) complexes of an N^C^N-coordinating pincer-like ligand featuring two lateral pyridine rings and a 6-membered carbene core. Their crystal structures display 1-dimensional chains with short π–π and M(II)⋯M(II) interactions. Such interactions also impact on the photophysical properties, with the Pt(II) complex being luminescent in the solid state at room temperature.

Graphical abstract: New N^C^N-coordinated Pd(ii) and Pt(ii) complexes of a tridentate N-heterocyclic carbene ligand featuring a 6-membered central ring: synthesis, structures and luminescence

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Supplementary files

Article information


Submitted
17 Jun 2016
Accepted
20 Jul 2016
First published
21 Jul 2016

Dalton Trans., 2016,45, 12644-12648
Article type
Communication

New N^C^N-coordinated Pd(II) and Pt(II) complexes of a tridentate N-heterocyclic carbene ligand featuring a 6-membered central ring: synthesis, structures and luminescence

J. Moussa, K. Haddouche, L. Chamoreau, H. Amouri and J. A. Gareth Williams, Dalton Trans., 2016, 45, 12644
DOI: 10.1039/C6DT02415G

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