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Issue 39, 2016
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Palladium-catalysed direct thiolation and selenation of aryl C–H bonds assisted by directing groups

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Abstract

Direct chalcogenation of aryl C–H bonds has attracted a lot of attention because arylcharcogen compounds represent useful building blocks in bioactive molecules and functional organic materials. Very recently, chelate-assisted intermolecular direct thiolation and selenation have been developed using various transition-metal catalysts such as palladium, rhodium, nickel, copper and ruthenium. In addition, an appropriate choice of directing group can be used to control the reaction sites. This highlight review focuses on the recent advances in catalytic C–H chalcogenation.

Graphical abstract: Palladium-catalysed direct thiolation and selenation of aryl C–H bonds assisted by directing groups

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Article information


Submitted
30 May 2016
Accepted
02 Aug 2016
First published
03 Aug 2016

Dalton Trans., 2016,45, 15278-15284
Article type
Frontier

Palladium-catalysed direct thiolation and selenation of aryl C–H bonds assisted by directing groups

M. Iwasaki and Y. Nishihara, Dalton Trans., 2016, 45, 15278
DOI: 10.1039/C6DT02167K

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