Issue 32, 2016

Accessing spin-crossover behaviour in iron(ii) complexes of N-confused scorpionate ligands

Abstract

The first examples of a class of N-confused tris(pyrazolyl)methane ‘scorpionate’ ligands have been prepared. The magnetic properties of their iron(II) tetrafluoroborate complexes are dictated by changing one substituent per ligand rather than three as is typical for normal scorpionate ligands.

Graphical abstract: Accessing spin-crossover behaviour in iron(ii) complexes of N-confused scorpionate ligands

Supplementary files

Article information

Article type
Communication
Submitted
13 May 2016
Accepted
20 Jul 2016
First published
20 Jul 2016

Dalton Trans., 2016,45, 12639-12643

Accessing spin-crossover behaviour in iron(II) complexes of N-confused scorpionate ligands

J. R. Gardinier, A. R. Treleven, K. J. Meise and Sergey. V. Lindeman, Dalton Trans., 2016, 45, 12639 DOI: 10.1039/C6DT01898J

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