[BEDT-TTF][Fe(C2O4)Cl2]: an organic–inorganic hybrid semiconductive antiferromagnet

B. Zhang; Y. Zhang; Z. Wang; D. Yang; Z. Gao; D. Wang; Y. Guo; D. Zhu; T. Mori

doi:10.1039/C6DT01845A

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[BEDT-TTF][Fe(C₂O₄)Cl₂]: an organic–inorganic hybrid semiconductive antiferromagnet†

B. Zhang,*^a Y. Zhang,^b Z. Wang,^c D. Yang,^d Z. Gao,^e D. Wang,^f Y. Guo,^f D. Zhu^a and T. Mori^g

Author affiliations

* Corresponding authors

^a Organic Solid Laboratory, CMS & BNLMS, Institute of Chemistry, Chinese Academy of Sciences, Beijing, P. R. China
E-mail: zhangbin@iccasa.c.cn
Fax: +86-10-62559373
Tel: +86-10-62558982

^b Institute of Condensed Matter and Material Physics, School of Physics, Peking University, Beijing, P. R. China

^c BNLMS, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, P. R. China

^d Institute of Chemistry, Chinese Academy of Sciences, Beijing, P. R. China

^e BSRF, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100047, P. R. China

^f National Center for Nanoscience and Technology, Beijing, P. R. China

^g Department of Organic and Polymeric Materials, Tokyo Institute of Technology, O-Okayama 2-12-1, Meguro-Ku, Tokyo 152-8552, Japan

Abstract

A radical cation salt composed of an organic donor, BEDT-TTF^1.0+, and a one-dimensional inorganic anion, [Fe(C₂O₄)Cl₂⁻]_n, was obtained by electrocrystallization, and was identified as a semiconductor with values of σ_300K = 3.0 × 10⁻⁵ S cm⁻¹. Spin-canted antiferromagnetic long-range ordering was observed at 5.5 K from ZFCM/FCM/RM measurement and confirmed using AC measurement.

This article is part of the themed collection: Molecular Spintronics : The role of Coordination Chemistry

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Article information

DOI: https://doi.org/10.1039/C6DT01845A
Article type: Communication
Submitted: 10 May 2016
Accepted: 16 Jun 2016
First published: 17 Jun 2016

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Dalton Trans., 2016,45, 16561-16565

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[BEDT-TTF][Fe(C₂O₄)Cl₂]: an organic–inorganic hybrid semiconductive antiferromagnet

B. Zhang, Y. Zhang, Z. Wang, D. Yang, Z. Gao, D. Wang, Y. Guo, D. Zhu and T. Mori, Dalton Trans., 2016, 45, 16561 DOI: 10.1039/C6DT01845A

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