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Issue 40, 2016
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Group 5 chemistry supported by β-diketiminate ligands

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Abstract

β-Diketiminate (BDI) ligands are widely used supporting ligands in modern organometallic chemistry and are capable of stabilizing various metal complexes in multiple oxidation states and coordination environments. This review describes recent advances in the chemistry of group 5 metals, namely vanadium, niobium and tantalum supported by the BDI ligand framework. Special emphasis is put on the reactivity of low-valent complexes, as well as low-coordinate complexes containing reactive multiply bonded groups, such as alkylidene, imido and nitrido groups.

Graphical abstract: Group 5 chemistry supported by β-diketiminate ligands

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Article information


Submitted
12 May 2016
Accepted
10 Jun 2016
First published
21 Jun 2016

Dalton Trans., 2016,45, 15725-15745
Article type
Perspective

Group 5 chemistry supported by β-diketiminate ligands

S. Hohloch, B. M. Kriegel, R. G. Bergman and J. Arnold, Dalton Trans., 2016, 45, 15725
DOI: 10.1039/C6DT01770C

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