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Issue 42, 2016
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Magnetic frustration in a hexaazatrinaphthylene-bridged trimetallic dysprosium single-molecule magnet

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Abstract

The synthesis, structure and magnetic properties of the HAN-bridged tri-dysprosium complex [{(thd)3Dy}3HAN] (1) are described. The complex is an SMM that shows two relaxation processes owing to the presence of two geometrically distinct Dy3+ sites in 1. Ab initio calculations reveal that the magnetic ground state of 1 is characterized by magnetic frustration.

Graphical abstract: Magnetic frustration in a hexaazatrinaphthylene-bridged trimetallic dysprosium single-molecule magnet

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Article information


Submitted
05 May 2016
Accepted
20 May 2016
First published
23 May 2016

This article is Open Access

Dalton Trans., 2016,45, 16556-16560
Article type
Communication
Author version available

Magnetic frustration in a hexaazatrinaphthylene-bridged trimetallic dysprosium single-molecule magnet

R. Grindell, V. Vieru, T. Pugh, L. F. Chibotaru and R. A. Layfield, Dalton Trans., 2016, 45, 16556
DOI: 10.1039/C6DT01763K

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