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Issue 17, 2016
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Addition of alkynes to digermynes: experimental insight into the reaction pathway

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Abstract

The addition of an alkynyl cyclopropyl mechanistic probe to a digermyne did not lead to any ring-opened rearrangement products indicating that the reaction pathway does not involve any vinylic radicals or cations and providing experimental insight into the addition of alkynes to digermynes.

Graphical abstract: Addition of alkynes to digermynes: experimental insight into the reaction pathway

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Publication details

The article was received on 15 Mar 2016, accepted on 01 Apr 2016 and first published on 11 Apr 2016


Article type: Communication
DOI: 10.1039/C6DT01015F
Dalton Trans., 2016,45, 7226-7230

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    Addition of alkynes to digermynes: experimental insight into the reaction pathway

    N. Y. Tashkandi, L. C. Pavelka, C. A. Caputo, P. D. Boyle, P. P. Power and K. M. Baines, Dalton Trans., 2016, 45, 7226
    DOI: 10.1039/C6DT01015F

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