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Issue 37, 2016
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Activation of CS2 by a “masked” terminal nickel sulfide

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Abstract

The “masked” terminal nickel sulfide complexes [K(L)][(LtBu)NiII(S)] (LtBu = {(2,6-iPr2C6H3)NC(tBu)}2CH, L = 18-crown-6, 2,2,2-cryptand) activate CS2 to give the trithiocarbonate products [(LtBu)NiII(S,S2-CS3)] or [(S,S2-CS3)NiII{S,S2-CS2(LtBu)}], further confirming the nucleophilicity of the sulfide (S2−) ligand in these complexes.

Graphical abstract: Activation of CS2 by a “masked” terminal nickel sulfide

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Publication details

The article was received on 04 Mar 2016, accepted on 25 Apr 2016 and first published on 26 Apr 2016


Article type: Communication
DOI: 10.1039/C6DT00885B
Dalton Trans., 2016,45, 14508-14510

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    Activation of CS2 by a “masked” terminal nickel sulfide

    N. J. Hartmann, G. Wu and Trevor. W. Hayton, Dalton Trans., 2016, 45, 14508
    DOI: 10.1039/C6DT00885B

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