Issue 28, 2016
From the journal:

Dalton Transactions

A 3-D net based on weak metallophilic (Cu⋯Cu) interactions†

Jian Zhou,*ad   Xiaofeng Tan,a   Feilong Hu,b   Hua-Hong Zou,c   Filipe A. Almeida Paz,d   Lianshe Fu*e  and  Rongqing Zhaoa  

* Corresponding authors

a College of Chemistry, Chongqing Normal University, Chongqing, P. R. China
E-mail: Jianzhou888888@163.com

b College of Chemistry and Ecological Engineering, Guangxi University for Nationalities, Nanning 530006, China

c Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources(Ministry of Education of China), School of Chemistry and Chemical Engineering of Guangxi Normal University, Guilin 541004, P.R. China

d Department of Chemistry, University of Aveiro, CICECO-Aveiro Institute of Materials, 3810-193, Aveiro, Portugal

e Department of Physics and CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-193, Aveiro, Portugal

Abstract

A novel 3-D binary copper(I) polymer [Cu(IN)]n (1, IN = isonicotinate) has been solvothermally synthesized. 1-D [Cu(IN)] chains of 1 are interconnected by weak metallophilic (Cu⋯Cu) interactions to form a 3-D net. The theoretical band structure and photocatalytic and fluorescence properties have also been studied.

Graphical abstract: A 3-D net based on weak metallophilic (Cu⋯Cu) interactions

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Article information

DOI
https://doi.org/10.1039/C6DT00883F
Article type
Communication
Submitted
04 Mar 2016
Accepted
31 Mar 2016
First published
31 Mar 2016

Dalton Trans., 2016,45, 11292-11296

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A 3-D net based on weak metallophilic (Cu⋯Cu) interactions

J. Zhou, X. Tan, F. Hu, H. Zou, F. A. Almeida Paz, L. Fu and R. Zhao, Dalton Trans., 2016, 45, 11292 DOI: 10.1039/C6DT00883F

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