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Issue 17, 2016
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Redox-mediated reactions of vinylferrocene: toward redox auxiliaries

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Abstract

Chemical redox reactions have been exploited to transform unreactive vinylferrocene into a powerful dienophile for the Diels–Alder reaction and reactive substrate for thiol addition reactions upon conversion to its ferrocenium state. We have further investigated the ability of these reactions to facilitate redox-auxiliary-like reactivity by further hydrogenolyisis of the Diels–Alder adduct to the corresponding cyclopentane derivative.

Graphical abstract: Redox-mediated reactions of vinylferrocene: toward redox auxiliaries

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Article information


Submitted
04 Mar 2016
Accepted
29 Mar 2016
First published
11 Apr 2016

This article is Open Access

Dalton Trans., 2016,45, 7220-7225
Article type
Communication

Redox-mediated reactions of vinylferrocene: toward redox auxiliaries

A. A. Wiles, X. Zhang, B. Fitzpatrick, D. Long, S. A. Macgregor and G. Cooke, Dalton Trans., 2016, 45, 7220
DOI: 10.1039/C6DT00875E

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