Issue 18, 2016
From the journal:

Dalton Transactions

Experimental and theoretical studies of Si–Cl and Ge–Cl σ-bond activation reactions by iridium-hydride†

H. Kameo,*a   K. Ikeda,a   S. Sakaki,b   S. Takemoto,a   H. Nakazawac  and  H. Matsuzakaa  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Gakuen-cho 1-1, Naka-ku, Sakai, Osaka 599-8531, Japan
E-mail: h.kameo@c.s.osakafu-u.ac.jp

b Fukui Institute for Fundamental Chemistry, Kyoto University, Takano-nishihiraki-cho 34-4, Sakyo-ku, Kyoto 606-8103, Japan

c Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto 3-3-138, Sumiyoshi-ku, Osaka 558-8585, Japan

Abstract

We report the iridium hydride-mediated Si–Cl and Ge–Cl σ-bond activation in a low-polarity toluene solution owing to diphosphine-chelation, in which the Si–Cl and Ge–Cl σ-bonds are readily cleaved through an SN2-type pathway via the formation of a free chloride anion.

Graphical abstract: Experimental and theoretical studies of Si–Cl and Ge–Cl σ-bond activation reactions by iridium-hydride

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Article information

DOI
https://doi.org/10.1039/C6DT00003G
Article type
Paper
Submitted
01 Jan 2016
Accepted
18 Feb 2016
First published
19 Feb 2016

Dalton Trans., 2016,45, 7570-7580

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Experimental and theoretical studies of Si–Cl and Ge–Cl σ-bond activation reactions by iridium-hydride

H. Kameo, K. Ikeda, S. Sakaki, S. Takemoto, H. Nakazawa and H. Matsuzaka, Dalton Trans., 2016, 45, 7570 DOI: 10.1039/C6DT00003G

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