Jump to main content
Jump to site search

Issue 17, 2016
Previous Article Next Article

Characterization of the [3Fe–4S]0/1+ cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses

Author affiliations

Abstract

The D14C variant of Pyrococcus furiosus ferredoxin provides an extraordinary framework to investigate a [3Fe–4S] cluster at two oxidation levels and compare the results to its physiologic [4Fe–4S] counterpart in the very same protein. Our spectroscopic and computational study reveals vibrational property changes related to the electronic and structural aspects of both Fe–S clusters.

Graphical abstract: Characterization of the [3Fe–4S]0/1+ cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses

Back to tab navigation

Supplementary files

Publication details

The article was received on 06 Dec 2015, accepted on 20 Mar 2016 and first published on 23 Mar 2016


Article type: Communication
DOI: 10.1039/C5DT04760A
Author version
available:
Download author version (PDF)
Dalton Trans., 2016,45, 7215-7219

  •   Request permissions

    Characterization of the [3Fe–4S]0/1+ cluster from the D14C variant of Pyrococcus furiosus ferredoxin via combined NRVS and DFT analyses

    L. Lauterbach, L. B. Gee, V. Pelmenschikov, F. E. Jenney, S. Kamali, Y. Yoda, M. W. W. Adams and S. P. Cramer, Dalton Trans., 2016, 45, 7215
    DOI: 10.1039/C5DT04760A

Search articles by author

Spotlight

Advertisements