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Issue 6, 2016
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The polyoxo-22-palladate(ii), [Na2Pd II22O12(AsVO4)15(AsVO3OH)]25−

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Abstract

The polyoxo-22-palladate [Na2PdII22O12(AsVO4)15(AsVO3OH)]25− (1), which represents a novel polyoxo-noble-metalate structural type, was synthesized by reaction of Pd2+ and AsO43− ions in aqueous solution. Polyanion 1 comprises two {NaPd11} units linked by two arsenate bridges, and hence represents the first example of a defect, monolacunary {Pd11} polyoxopalladate nanocube with arsenate capping groups. The title polyanion was characterized in the solid state as well as by theoretical calculations.

Graphical abstract: The polyoxo-22-palladate(ii), [Na2PdII22O12(AsVO4)15(AsVO3OH)]25−

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Supplementary files

Article information


Submitted
17 Nov 2015
Accepted
14 Dec 2015
First published
13 Jan 2016

Dalton Trans., 2016,45, 2394-2398
Article type
Communication

The polyoxo-22-palladate(II), [Na2PdII22O12(AsVO4)15(AsVO3OH)]25−

N. V. Izarova, Z. Lin, P. Yang, A. Kondinski, N. Vankova, T. Heine and U. Kortz, Dalton Trans., 2016, 45, 2394
DOI: 10.1039/C5DT04526F

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