Issue 3, 2016
From the journal:

Dalton Transactions

1,2,4-Diazaphospholide complexes of yttrium(iii), dysprosium(iii), erbium(iii), and europium(ii,iii): synthesis, X-ray structural characterization, and EPR analysis†

Yongli Wang,a   Wenzhen Guo,a   Dongling Liu,a   Ying Yangb  and  Wenjun Zheng*ac  

* Corresponding authors

a Institute of Organic Chemistry & College of Chemical and Materials Science, Shanxi Normal University, Gongyuan Street 1, Linfen, Shanxi Province, China
E-mail: wjzheng@sxnu.edu.cn, wjzheng_sxnu@qq.com

b School of Chemistry and Chemical Engineering Central South University, Lushannan Road 932, Changsha, Hunan Province 410083, People's Republic of China

c Key Laboratory of Magnetic Molecules and Magnetic Information Materials, Ministry of Education, Gongyuan Street 1, Linfen, Shanxi Province, China

Abstract

Several structurally characterized heteroleptic, charge-separated heterobimetallic, and polymeric alkali metal ate complexes of 1,2,4-diazaphospholide Y(III), Dy(III), Er(III), Eu(III), and Eu(II) were prepared via the reaction of MCl3 and K[3,5-R2dp] in varied ratios at 200–220 °C (M = Y, Dy, Er, Eu; R = tBu, Ph).

Graphical abstract: 1,2,4-Diazaphospholide complexes of yttrium(iii), dysprosium(iii), erbium(iii), and europium(ii,iii): synthesis, X-ray structural characterization, and EPR analysis

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Article information

DOI
https://doi.org/10.1039/C5DT04285B
Article type
Communication
Submitted
31 Oct 2015
Accepted
04 Dec 2015
First published
07 Dec 2015

Dalton Trans., 2016,45, 899-903

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1,2,4-Diazaphospholide complexes of yttrium(III), dysprosium(III), erbium(III), and europium(II,III): synthesis, X-ray structural characterization, and EPR analysis

Y. Wang, W. Guo, D. Liu, Y. Yang and W. Zheng, Dalton Trans., 2016, 45, 899 DOI: 10.1039/C5DT04285B

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