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Issue 13, 2016
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A stable open-shell redox active ditopic ligand

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Abstract

Herein we describe the synthesis, structure and electronic properties of an unusual redox-active ditopic ligand with a stable open-shell configuration. This stable phenoxyl radical features intense and very low energy electronic transitions in the near infrared (NIR) part of the spectrum and is structurally set up to strongly spin couple coordinated transition metal ions in [2 × 2] grid-type structures.

Graphical abstract: A stable open-shell redox active ditopic ligand

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Publication details

The article was received on 16 Oct 2015, accepted on 02 Mar 2016 and first published on 02 Mar 2016


Article type: Communication
DOI: 10.1039/C5DT04061B
Dalton Trans., 2016,45, 5460-5463

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    A stable open-shell redox active ditopic ligand

    N. M. Bonanno, A. J. Lough, K. E. Prosser, C. J. Walsby, P. K. Poddutoori and M. T. Lemaire, Dalton Trans., 2016, 45, 5460
    DOI: 10.1039/C5DT04061B

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