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Issue 13, 2016
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A stable open-shell redox active ditopic ligand

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Abstract

Herein we describe the synthesis, structure and electronic properties of an unusual redox-active ditopic ligand with a stable open-shell configuration. This stable phenoxyl radical features intense and very low energy electronic transitions in the near infrared (NIR) part of the spectrum and is structurally set up to strongly spin couple coordinated transition metal ions in [2 × 2] grid-type structures.

Graphical abstract: A stable open-shell redox active ditopic ligand

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Supplementary files

Article information


Submitted
16 Oct 2015
Accepted
02 Mar 2016
First published
02 Mar 2016

Dalton Trans., 2016,45, 5460-5463
Article type
Communication

A stable open-shell redox active ditopic ligand

N. M. Bonanno, A. J. Lough, K. E. Prosser, C. J. Walsby, P. K. Poddutoori and M. T. Lemaire, Dalton Trans., 2016, 45, 5460
DOI: 10.1039/C5DT04061B

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