Issue 2, 2016

Trifluoromethylation of thiophenols and thiols with sodium trifluoromethanesulfinate and iodine pentoxide

Abstract

A selective and facile trifluoromethylation process for a wide range of thiophenols and thiols under metal free conditions has been developed using two simple and safe solids, sodium trifluoro-methanesulfinate and iodine pentoxide, via the radical process.

Graphical abstract: Trifluoromethylation of thiophenols and thiols with sodium trifluoromethanesulfinate and iodine pentoxide

Supplementary files

Article information

Article type
Communication
Submitted
15 Sep 2015
Accepted
22 Oct 2015
First published
26 Oct 2015

Catal. Sci. Technol., 2016,6, 417-421

Trifluoromethylation of thiophenols and thiols with sodium trifluoromethanesulfinate and iodine pentoxide

J. Ma, W. Yi, G. Lu and C. Cai, Catal. Sci. Technol., 2016, 6, 417 DOI: 10.1039/C5CY01561H

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