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Issue 1, 2016
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Continuous flow hydrogenation of nitroarenes, azides and alkenes using maghemite–Pd nanocomposites

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Abstract

Maghemite-supported ultra-fine Pd (1–3 nm) nanoparticles, prepared by a simple co-precipitation method, find application in the catalytic continuous flow hydrogenation of nitroarenes, azides, and alkenes wherein they play an important role in the reduction of various functional groups on the surface of maghemite with catalyst loading (~6 wt% Pd). The salient features of the protocol include expeditious formation of reduced products in high yields under near ambient conditions with recycling of the catalyst (up to 12 cycles) without any decrease in selectivity and yield.

Graphical abstract: Continuous flow hydrogenation of nitroarenes, azides and alkenes using maghemite–Pd nanocomposites

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Article information


Submitted
25 Jun 2015
Accepted
03 Sep 2015
First published
07 Sep 2015

Catal. Sci. Technol., 2016,6, 152-160
Article type
Paper

Continuous flow hydrogenation of nitroarenes, azides and alkenes using maghemite–Pd nanocomposites

A. K. Rathi, M. B. Gawande, V. Ranc, J. Pechousek, M. Petr, K. Cepe, R. S. Varma and R. Zboril, Catal. Sci. Technol., 2016, 6, 152
DOI: 10.1039/C5CY00956A

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