Jump to main content
Jump to site search

Issue 11, 2016
Previous Article Next Article

Lanthanide-directed synthesis of luminescent self-assembly supramolecular structures and mechanically bonded systems from acyclic coordinating organic ligands

Author affiliations

Abstract

Herein some examples of the use of lanthanide ions (f-metal ions) to direct the synthesis of luminescent self-assembly systems (architectures) will be discussed. This area of lanthanide supramolecular chemistry is fast growing, thanks to the unique physical (magnetic and luminescent) and coordination properties of the lanthanides, which are often transferred to the resulting supermolecule. The emphasis herein will be on systems that are luminescent, and hence, generated by using either visibly emitting ions (such as EuIII, TbIII and SmIII) or near infrared emitting ions (like NdIII, YbIII and ErIII), formed through the use of templating chemistry, by employing structurally simple ligands, possessing oxygen and nitrogen coordinating moieties. As the lanthanides have high coordination requirements, their use often allows for the formation of coordination compounds and supramolecular systems such as bundles, grids, helicates and interlocked molecules that are not synthetically accessible through the use of other commonly used templating ions such as transition metal ions. Hence, the use of the rare-earth metal ions can lead to the formation of unique and stable species in both solution and in the solid state, as well as functional and responsive structures.

Graphical abstract: Lanthanide-directed synthesis of luminescent self-assembly supramolecular structures and mechanically bonded systems from acyclic coordinating organic ligands

Back to tab navigation

Article information


Submitted
17 Feb 2016
First published
03 May 2016

Chem. Soc. Rev., 2016,45, 3244-3274
Article type
Review Article
Author version available

Lanthanide-directed synthesis of luminescent self-assembly supramolecular structures and mechanically bonded systems from acyclic coordinating organic ligands

D. E. Barry, D. F. Caffrey and T. Gunnlaugsson, Chem. Soc. Rev., 2016, 45, 3244
DOI: 10.1039/C6CS00116E

Social activity

Search articles by author

Spotlight

Advertisements