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Issue 36, 2016
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The 3D [(Cu2Br2){μ-EtS(CH2)4SEt}]n material: a rare example of a coordination polymer exhibiting triplet–triplet annihilation

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Abstract

EtS(CH2)4SEt, L1, forms with CuI a luminescent 2D polymer [Cu4I4{μ-L1}2]n (CP1), which exhibits no triplet excitation energy migration, but with CuBr, it forms a 3D material (CP2), [(Cu2Br2){μ-L1}]n consisting of parallel (Cu2Br2S2)n layers bridged by L1's. CP2 shows T1–T1 annihilation at 298 K but not at 77 K.

Graphical abstract: The 3D [(Cu2Br2){μ-EtS(CH2)4SEt}]n material: a rare example of a coordination polymer exhibiting triplet–triplet annihilation

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Supplementary files

Article information


Submitted
07 Jul 2016
Accepted
24 Aug 2016
First published
25 Aug 2016

Phys. Chem. Chem. Phys., 2016,18, 24845-24849
Article type
Communication

The 3D [(Cu2Br2){μ-EtS(CH2)4SEt}]n material: a rare example of a coordination polymer exhibiting triplet–triplet annihilation

A. Bonnot, P. Karsenti, F. Juvenal, C. Golz, C. Strohmann, D. Fortin, M. Knorr and P. D. Harvey, Phys. Chem. Chem. Phys., 2016, 18, 24845
DOI: 10.1039/C6CP04728A

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