Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 27, 2016
Previous Article Next Article

Characterization of dimethylsulfoxide/glycerol mixtures: a binary solvent system for the study of “friction-dependent” chemical reactivity

Author affiliations

Abstract

The properties of binary mixtures of dimethylsulfoxide and glycerol, measured using several techniques, are reported. Special attention is given to those properties contributing or affecting chemical reactions. In this respect the investigated mixture behaves as a relatively simple solvent and it is especially well suited for studies on the influence of viscosity on chemical reactivity. This is due to the relative invariance of the dielectric properties of the mixture. However, special caution must be taken with specific solvation, as the hydrogen-bonding properties of the solvent change with the molar fraction of glycerol.

Graphical abstract: Characterization of dimethylsulfoxide/glycerol mixtures: a binary solvent system for the study of “friction-dependent” chemical reactivity

Back to tab navigation

Supplementary files

Article information


Submitted
04 May 2016
Accepted
09 Jun 2016
First published
10 Jun 2016

Phys. Chem. Chem. Phys., 2016,18, 18460-18469
Article type
Paper

Characterization of dimethylsulfoxide/glycerol mixtures: a binary solvent system for the study of “friction-dependent” chemical reactivity

G. Angulo, M. Brucka, M. Gerecke, G. Grampp, D. Jeannerat, J. Milkiewicz, Y. Mitrev, C. Radzewicz, A. Rosspeintner, E. Vauthey and P. Wnuk, Phys. Chem. Chem. Phys., 2016, 18, 18460
DOI: 10.1039/C6CP02997C

Social activity

Search articles by author

Spotlight

Advertisements