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Issue 16, 2016
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Bistable N–H⋯N hydrogen bonds for reversibly modulating the dynamic motion in an organic co-crystal

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Abstract

Bistable N–H⋯N hydrogen bonds between rotors and stators enable delicate modulation of dynamic molecular motion by slowing down the fast rotation in a N–H⋯N hydrogen-bonded organic co-crystal of 1,2-diazabicyclo(2.2.2)octane bis(thiourea), which has been elucidated by the combination of variable-temperature (VT) X-ray structure analyses and VT solid-state nuclear magnetic resonance techniques.

Graphical abstract: Bistable N–H⋯N hydrogen bonds for reversibly modulating the dynamic motion in an organic co-crystal

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Article information


Submitted
17 Feb 2016
Accepted
24 Mar 2016
First published
24 Mar 2016

Phys. Chem. Chem. Phys., 2016,18, 10868-10872
Article type
Communication

Bistable N–H⋯N hydrogen bonds for reversibly modulating the dynamic motion in an organic co-crystal

C. Ji, S. Li, F. Deng, S. Liu, M. A. Asghar, Z. Sun, M. Hong and J. Luo, Phys. Chem. Chem. Phys., 2016, 18, 10868
DOI: 10.1039/C6CP01073C

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