Issue 15, 2016
From the journal:

Physical Chemistry Chemical Physics

Complete ligand loss in electron ionization of the weakly bound organometallic tungsten hexacarbonyl dimer†

Michael Neustetter,a   Andreas Mauracher,a   Paulo Limão-Vieira*b  and  Stephan Denifl*a  

* Corresponding authors

a Institut für Ionenphysik und Angewandte Physik, Leopold Franzens Universität Innsbruck, Technikerstrasse 25, A-6020 Innsbruck, Austria
E-mail: Stephan.Denifl@uibk.ac.at

b Laboratório de Colisões Atómicas e Moleculares, CEFITEC, Departamento de Física, Faculdade de Ciências e Tecnologia, Universidade NOVA de Lisboa, 2829-516 Caparica, Portugal
E-mail: plimaovieira@fct.unl.pt

Abstract

We observed the bare W2+ metal cation upon electron ionization of the weakly bound W(CO)6 dimer. This metal cation can be only observed due to the fast conversion of the weak cluster bond into a strong covalent bond between the metal moieties.

Graphical abstract: Complete ligand loss in electron ionization of the weakly bound organometallic tungsten hexacarbonyl dimer

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Article information

DOI
https://doi.org/10.1039/C6CP00558F
Article type
Communication
Submitted
26 Jan 2016
Accepted
10 Mar 2016
First published
14 Mar 2016

Phys. Chem. Chem. Phys., 2016,18, 9893-9896

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Complete ligand loss in electron ionization of the weakly bound organometallic tungsten hexacarbonyl dimer

M. Neustetter, A. Mauracher, P. Limão-Vieira and S. Denifl, Phys. Chem. Chem. Phys., 2016, 18, 9893 DOI: 10.1039/C6CP00558F

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