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Issue 46, 2016
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Absolute asymmetric synthesis of a sanguinarine derivative through crystal–solution interactions

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Abstract

A new construction reaction for the absolute asymmetric synthesis of a sanguinarine derivative was realized by crystal–solution interactions. A stochastic outcome with high enantiomeric excess (ee%) values (up to 100%) was observed under cooling crystallization, while preferential chiral amplification was observed with Viedma ripening.

Graphical abstract: Absolute asymmetric synthesis of a sanguinarine derivative through crystal–solution interactions

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Article information


Submitted
12 Aug 2016
Accepted
29 Sep 2016
First published
29 Sep 2016

CrystEngComm, 2016,18, 8834-8837
Article type
Communication

Absolute asymmetric synthesis of a sanguinarine derivative through crystal–solution interactions

Q. Zhang, L. Jia, J. Wang and X. Mei, CrystEngComm, 2016, 18, 8834
DOI: 10.1039/C6CE01765G

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