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Issue 30, 2016
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N-Alkyl ammonium resorcinarene polyiodides

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Abstract

Four N-alkyl ammonium resorcinarene halides incorporating polyiodides were obtained and structurally analyzed by single crystal X-ray crystallography. The unexpected formation of triiodides and pentaiodide anions in these structures was assumed to be the result of the heterolytic dissociation of molecular iodine (I2) in the presence of electron donors in the N-alkyl ammonium resorcinarene halide system, from which I further binds one or two I2 molecules resulting in I3 or I5 species, respectively.

Graphical abstract: N-Alkyl ammonium resorcinarene polyiodides

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Publication details

The article was received on 26 May 2016, accepted on 16 Jun 2016 and first published on 17 Jun 2016


Article type: Paper
DOI: 10.1039/C6CE01229A
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Citation: CrystEngComm, 2016,18, 5724-5727
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    N-Alkyl ammonium resorcinarene polyiodides

    F. Pan, N. K. Beyeh, R. H. A. Ras and K. Rissanen, CrystEngComm, 2016, 18, 5724
    DOI: 10.1039/C6CE01229A

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