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Two halogen bonded cocrystals of N-bromosuccinimide and 4,4′-bipyridine, with stoichiometric ratios 1 : 1 and 2 : 1, have been synthesized and characterized. We present the first mechanochemical cocrystallization of N-bromosuccinimide.

Graphical abstract: Halogen bonding of N-bromosuccinimide by grinding

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