Issue 40, 2016
From the journal:

CrystEngComm

An alkali-ion insertion approach to structurally transform metal–organic frameworks†

Yue-Qiao Hu,a   Mu-Qing Li,a   Teng Li,a   Yan-Yan Wang,a   Zhiping Zhengb  and  Yan-Zhen Zheng*a  

* Corresponding authors

a Frontier Institute of Science and Technology (FIST) and School of Science, Xi'an Jiaotong University, Xi'an 710054, China
E-mail: zheng.yanzhen@xjtu.edu.cn
Web: http://gr.xjtu.edu.cn/web/zheng.yanzhen/home

b Department of Chemistry and Biochemistry, University of Arizona, Tucson, Arizona 85721, USA

Abstract

The insertion of alkali metal ions into a prevalent lanthanide-carboxylate coordination motif in heterometallic 3d–4f metal–organic frameworks (MOFs) leads to new MOFs whose structures are sensitively dependent on the size of the alkali ions used and with significantly enhanced effective free crystallographic volume.

Graphical abstract: An alkali-ion insertion approach to structurally transform metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C6CE00540C
Article type
Communication
Submitted
09 Mar 2016
Accepted
08 Sep 2016
First published
08 Sep 2016

CrystEngComm, 2016,18, 7680-7684

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An alkali-ion insertion approach to structurally transform metal–organic frameworks

Y. Hu, M. Li, T. Li, Y. Wang, Z. Zheng and Y. Zheng, CrystEngComm, 2016, 18, 7680 DOI: 10.1039/C6CE00540C

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