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Issue 24, 2016
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Origin of brown coloration in top-seeded solution grown SrTiO3 crystals

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Abstract

SrTiO3 crystals grown by the top-seeded solution growth method in air show different shades of light brown coloration, depending on the growth conditions. In the optical transmission spectrum this is manifested as a broad absorption, tailing off from the fundamental absorption edge into the visible range. The investigation by transmission electron microscopy reveals that the light brown crystals contain voids of varying sizes in the nanometer range. Using the found size density distribution, the light scattering caused by such nano-voids in SrTiO3 is calculated on the basis of the Mie theory. A good agreement with the measured optical spectra is found. It is proposed that the formation of the nano-voids is due to vacancy clustering.

Graphical abstract: Origin of brown coloration in top-seeded solution grown SrTiO3 crystals

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Publication details

The article was received on 29 Jan 2016, accepted on 09 May 2016 and first published on 09 May 2016


Article type: Paper
DOI: 10.1039/C6CE00247A
CrystEngComm, 2016,18, 4580-4586

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    Origin of brown coloration in top-seeded solution grown SrTiO3 crystals

    D. J. Kok, C. Guguschev, T. Markurt, M. Niu, R. Bertram, M. Albrecht and K. Irmscher, CrystEngComm, 2016, 18, 4580
    DOI: 10.1039/C6CE00247A

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