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Issue 22, 2016
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Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

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Abstract

A study of a copper-based metal–organic framework (MOF) synthesized by an electrochemical route is presented. Morphological and adsorption properties of the MOF synthesized as bulk powder and on supported copper surfaces were investigated. Differences in these properties and structural refinement studies indicate that when 4,4′,4′′-s-triazine-2,4,6-triyl-tribenzoic acid (H3TATB) is used as linker interpenetration can be prevented when the structure is grown on a surface.

Graphical abstract: Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

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Supplementary files

Article information


Submitted
15 Dec 2015
Accepted
11 Jan 2016
First published
11 Jan 2016

This article is Open Access

CrystEngComm, 2016,18, 4018-4022
Article type
Communication

Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

S. Sachdeva, A. Pustovarenko, E. J. R. Sudhölter, F. Kapteijn, L. C. P. M. de Smet and J. Gascon, CrystEngComm, 2016, 18, 4018
DOI: 10.1039/C5CE02462E

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