The MnO4−/MnO42− redox couple has a positive redox potential, high electrochemical reversibility and high solubility, up to 3.62 M at room temperature. Careful optimization of the electrolyte composition and the potential limits eliminates the side reactions, making this redox couple an attractive option for alkaline redox flow batteries.
A. N. Colli, P. Peljo and H. H. Girault, Chem. Commun., 2016, 52, 14039 DOI: 10.1039/C6CC08070G
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