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Issue 99, 2016
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Highly efficient reduction of carbon dioxide with a borane catalyzed by bis(phosphinite) pincer ligated palladium thiolate complexes

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Abstract

Highly efficient catalytic reduction of CO2 with catecholborane has been developed by using bis(phosphinite) pincer ligated palladium thiolate complexes. Turnover frequencies up to 1780 h−1 have been achieved at room temperature under an atmospheric pressure of CO2. These thiolate complexes represent the most efficient homogeneous catalysts known to date for the reduction of CO2 to methanol under mild conditions.

Graphical abstract: Highly efficient reduction of carbon dioxide with a borane catalyzed by bis(phosphinite) pincer ligated palladium thiolate complexes

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Article information


Submitted
03 Oct 2016
Accepted
15 Nov 2016
First published
16 Nov 2016

Chem. Commun., 2016,52, 14262-14265
Article type
Communication

Highly efficient reduction of carbon dioxide with a borane catalyzed by bis(phosphinite) pincer ligated palladium thiolate complexes

Q. Ma, T. Liu, S. Li, J. Zhang, X. Chen and H. Guan, Chem. Commun., 2016, 52, 14262
DOI: 10.1039/C6CC07987C

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