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Issue 99, 2016
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Highly efficient reduction of carbon dioxide with a borane catalyzed by bis(phosphinite) pincer ligated palladium thiolate complexes

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Abstract

Highly efficient catalytic reduction of CO2 with catecholborane has been developed by using bis(phosphinite) pincer ligated palladium thiolate complexes. Turnover frequencies up to 1780 h−1 have been achieved at room temperature under an atmospheric pressure of CO2. These thiolate complexes represent the most efficient homogeneous catalysts known to date for the reduction of CO2 to methanol under mild conditions.

Graphical abstract: Highly efficient reduction of carbon dioxide with a borane catalyzed by bis(phosphinite) pincer ligated palladium thiolate complexes

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Publication details

The article was received on 03 Oct 2016, accepted on 15 Nov 2016 and first published on 16 Nov 2016


Article type: Communication
DOI: 10.1039/C6CC07987C
Chem. Commun., 2016,52, 14262-14265

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    Highly efficient reduction of carbon dioxide with a borane catalyzed by bis(phosphinite) pincer ligated palladium thiolate complexes

    Q. Ma, T. Liu, S. Li, J. Zhang, X. Chen and H. Guan, Chem. Commun., 2016, 52, 14262
    DOI: 10.1039/C6CC07987C

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