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Issue 87, 2016
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Electrochemically active porous organic polymers based on corannulene

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Abstract

For the first time, porous organic polymers (POPs) based on the smallest buckybowl, corannulene (BB-POPs) have been synthesized. Three POPs were synthesised via Sonogashira co-polymerization of 1,2,5,6-tetrabromocorannulene and alkyne linkers. BB-POP-3 exhibits the highest surface area (SABET = 560 m2 gāˆ’1) and CO2 adsorption of 11.7 wt%, while they retain the redox properties of corannulene.

Graphical abstract: Electrochemically active porous organic polymers based on corannulene

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Supplementary files

Article information


Submitted
11 Sep 2016
Accepted
11 Oct 2016
First published
11 Oct 2016

Chem. Commun., 2016,52, 12881-12884
Article type
Communication

Electrochemically active porous organic polymers based on corannulene

A. A. K. Karunathilake, C. M. Thompson, S. Perananthan, J. P. Ferraris and R. A. Smaldone, Chem. Commun., 2016, 52, 12881
DOI: 10.1039/C6CC07421A

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