Jump to main content
Jump to site search

Issue 80, 2016
Previous Article Next Article

Construction of the carbon–chalcogen (S, Se, Te) bond at the 2,6-positions of BODIPY via Stille cross-coupling reaction

Author affiliations

Abstract

Seven new 2-chalcogen- or 2,6-dichalcogen- (S, Se, Te) BODIPY derivatives were synthesized in good to excellent yields (55–95%) by a Pd-catalyzed C–heteroatom Stille cross-coupling reaction, overcoming the limitations of SNAr. The fluorophores show interesting tunable optical properties associated with the formation of a twisted intramolecular charge transfer excited state and competing intersystem crossing.

Graphical abstract: Construction of the carbon–chalcogen (S, Se, Te) bond at the 2,6-positions of BODIPY via Stille cross-coupling reaction

Back to tab navigation

Supplementary files

Article information


Submitted
23 Aug 2016
Accepted
06 Sep 2016
First published
16 Sep 2016

This article is Open Access

Chem. Commun., 2016,52, 11951-11954
Article type
Communication

Construction of the carbon–chalcogen (S, Se, Te) bond at the 2,6-positions of BODIPY via Stille cross-coupling reaction

E. Palao, T. Slanina and P. Klán, Chem. Commun., 2016, 52, 11951
DOI: 10.1039/C6CC06923A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:

  • For reproduction of material from NJC:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
  • For reproduction of material from PCCP:
    [Original citation] - Published by the PCCP Owner Societies.
  • For reproduction of material from PPS:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
  • For reproduction of material from all other RSC journals:
    [Original citation] - Published by The Royal Society of Chemistry.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.


Social activity

Search articles by author

Spotlight

Advertisements