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Issue 79, 2016
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Supramolecular assembly of cobaloxime on nanoring-coated carbon nanotubes: addressing the stability of the pyridine–cobalt linkage under hydrogen evolution turnover conditions

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Abstract

A carbon nanotube–cobaloxime nanohybrid was prepared through supramolecular assembly of tailored polymerizable amphiphiles, leading to the coordination of cobalt on pyridine-coated nanotubes. This material was used as a catalyst for hydrogen evolution in fully aqueous media. This study provides a definitive asset regarding the stability of the pyridine–cobalt axial bond under H2 evolution turnover conditions.

Graphical abstract: Supramolecular assembly of cobaloxime on nanoring-coated carbon nanotubes: addressing the stability of the pyridine–cobalt linkage under hydrogen evolution turnover conditions

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Publication details

The article was received on 22 Jul 2016, accepted on 01 Sep 2016 and first published on 12 Sep 2016


Article type: Communication
DOI: 10.1039/C6CC06059E
Chem. Commun., 2016,52, 11783-11786

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    Supramolecular assembly of cobaloxime on nanoring-coated carbon nanotubes: addressing the stability of the pyridine–cobalt linkage under hydrogen evolution turnover conditions

    S. Donck, J. Fize, E. Gravel, E. Doris and V. Artero, Chem. Commun., 2016, 52, 11783
    DOI: 10.1039/C6CC06059E

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