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Issue 83, 2016
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Visible-light-mediated generation of nitrile oxides for the photoredox synthesis of isoxazolines and isoxazoles

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Abstract

Visible-light photoredox catalysis enables the synthesis of biologically relevant isoxazolines and isoxazoles from hydroxyimino acids. The process shows broad functional group compatibility and mechanistic and computational studies support a visible-light-mediated generation of nitrile oxides by two sequential oxidative single electron transfer processes.

Graphical abstract: Visible-light-mediated generation of nitrile oxides for the photoredox synthesis of isoxazolines and isoxazoles

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Supplementary files

Article information


Submitted
21 Jul 2016
Accepted
21 Sep 2016
First published
21 Sep 2016

Chem. Commun., 2016,52, 12302-12305
Article type
Communication

Visible-light-mediated generation of nitrile oxides for the photoredox synthesis of isoxazolines and isoxazoles

T. D. Svejstrup, W. Zawodny, J. J. Douglas, D. Bidgeli, N. S. Sheikh and D. Leonori, Chem. Commun., 2016, 52, 12302
DOI: 10.1039/C6CC06029C

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