Reactions between [TcI(NO)X2(PPh3)2(CH3CN)] complexes (X = Cl, Br) and KCp form the pseudotetrahedral organotechnetium compounds [TcI(NO)(Cp)(PPh3)X]. The halide ligands can readily be replaced by other halides or organometallic ligands giving access to a novel family of technetium(I) compounds with the robust {Tc(NO)(Cp)(PPh3)}+ core.
J. Ackermann, A. Hagenbach and U. Abram, Chem. Commun., 2016, 52, 10285 DOI: 10.1039/C6CC05811F
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