Issue 64, 2016

Bis(mesitoyl)phosphinic acid: photo-triggered release of metaphosphorous acid in solution

Abstract

Bis(mesitoyl)phosphinic acid and its sodium salt display a unique photo-induced reactivity: both derivatives stepwise release two mesitoyl radicals and, remarkably, metaphosphorous acid (previously postulated as transient species in the gas phase), providing a new phosphorus-based reagent.

Graphical abstract: Bis(mesitoyl)phosphinic acid: photo-triggered release of metaphosphorous acid in solution

Supplementary files

Article information

Article type
Communication
Submitted
22 Jun 2016
Accepted
08 Jul 2016
First published
08 Jul 2016

Chem. Commun., 2016,52, 9917-9920

Bis(mesitoyl)phosphinic acid: photo-triggered release of metaphosphorous acid in solution

D. E. Fast, M. Zalibera, A. Lauer, A. Eibel, C. Schweigert, A. Kelterer, M. Spichty, D. Neshchadin, D. Voll, H. Ernst, Y. Liang, K. Dietliker, A. Unterreiner, C. Barner-Kowollik, H. Grützmacher and G. Gescheidt, Chem. Commun., 2016, 52, 9917 DOI: 10.1039/C6CC05219C

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