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Issue 64, 2016
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Bis(mesitoyl)phosphinic acid: photo-triggered release of metaphosphorous acid in solution

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Abstract

Bis(mesitoyl)phosphinic acid and its sodium salt display a unique photo-induced reactivity: both derivatives stepwise release two mesitoyl radicals and, remarkably, metaphosphorous acid (previously postulated as transient species in the gas phase), providing a new phosphorus-based reagent.

Graphical abstract: Bis(mesitoyl)phosphinic acid: photo-triggered release of metaphosphorous acid in solution

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Publication details

The article was received on 22 Jun 2016, accepted on 08 Jul 2016 and first published on 08 Jul 2016


Article type: Communication
DOI: 10.1039/C6CC05219C
Citation: Chem. Commun., 2016,52, 9917-9920

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    Bis(mesitoyl)phosphinic acid: photo-triggered release of metaphosphorous acid in solution

    D. E. Fast, M. Zalibera, A. Lauer, A. Eibel, C. Schweigert, A. Kelterer, M. Spichty, D. Neshchadin, D. Voll, H. Ernst, Y. Liang, K. Dietliker, A. Unterreiner, C. Barner-Kowollik, H. Grützmacher and G. Gescheidt, Chem. Commun., 2016, 52, 9917
    DOI: 10.1039/C6CC05219C

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