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Abstract | Cited by

The first intermolecular Pauson–Khand reaction, conducted using internal alkynylboronic esters, allows the installation of the boronic ester moiety at the β-position of the cyclopentenone with total regio- and stereoselectivity.

Graphical abstract: The Pauson–Khand reaction using alkynylboronic esters: solving a long-standing regioselectivity issue

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