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Issue 54, 2016
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High hydroxide conductivity in a chemically stable crystalline metal–organic framework containing a water-hydroxide supramolecular chain

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Abstract

A chemically stable cationic MOF encapsulating an in situ formed water-hydroxide supramolecular anionic chain is realized for high hydroxide (OH) ion conductivity in the solid-state (Type A). High OH ion conductivity and low activation energy of the MOF demonstrate the advantage of the in situ incorporation of OH ions to achieve efficient OH ion conduction in the solid-state.

Graphical abstract: High hydroxide conductivity in a chemically stable crystalline metal–organic framework containing a water-hydroxide supramolecular chain

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Publication details

The article was received on 26 May 2016, accepted on 07 Jun 2016 and first published on 07 Jun 2016


Article type: Communication
DOI: 10.1039/C6CC04436K
Citation: Chem. Commun., 2016,52, 8459-8462
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    High hydroxide conductivity in a chemically stable crystalline metal–organic framework containing a water-hydroxide supramolecular chain

    S. S. Nagarkar, B. Anothumakkool, A. V. Desai, M. M. Shirolkar, S. Kurungot and S. K. Ghosh, Chem. Commun., 2016, 52, 8459
    DOI: 10.1039/C6CC04436K

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