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Issue 54, 2016
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High hydroxide conductivity in a chemically stable crystalline metal–organic framework containing a water-hydroxide supramolecular chain

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Abstract

A chemically stable cationic MOF encapsulating an in situ formed water-hydroxide supramolecular anionic chain is realized for high hydroxide (OH) ion conductivity in the solid-state (Type A). High OH ion conductivity and low activation energy of the MOF demonstrate the advantage of the in situ incorporation of OH ions to achieve efficient OH ion conduction in the solid-state.

Graphical abstract: High hydroxide conductivity in a chemically stable crystalline metal–organic framework containing a water-hydroxide supramolecular chain

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Article information


Submitted
26 May 2016
Accepted
07 Jun 2016
First published
07 Jun 2016

Chem. Commun., 2016,52, 8459-8462
Article type
Communication

High hydroxide conductivity in a chemically stable crystalline metal–organic framework containing a water-hydroxide supramolecular chain

S. S. Nagarkar, B. Anothumakkool, A. V. Desai, M. M. Shirolkar, S. Kurungot and S. K. Ghosh, Chem. Commun., 2016, 52, 8459
DOI: 10.1039/C6CC04436K

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