Issue 59, 2016
From the journal:

Chemical Communications

Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands†

Nora Hellou,a   Claire Jahier-Diallo,‡b   Olivier Baslé,b   Monika Srebro-Hooper,c   Loïc Toupet,a   Thierry Roisnel,a   Elsa Caytan,a   Christian Roussel,d   Nicolas Vanthuyne,d   Jochen Autschbach,*e   Marc Mauduitb  and  Jeanne Crassous*a  

* Corresponding authors

a Institut des Sciences Chimiques de Rennes, UMR 6226, Institut de Physique de Rennes, UMR 6251, Campus de Beaulieu, CNRS-Université de Rennes 1, 35042 Rennes Cedex, France
E-mail: jeanne.crassous@univ-rennes1.fr

b Ecole Nationale Supérieure de Chimie de Rennes, CNRS, UMR 6226, 11 Allée de Beaulieu, CS 50837, 35708 Rennes Cedex 7, France

c Department of Theoretical Chemistry, Faculty of Chemistry, Jagiellonian University, R. Ingardena 3, 30-060 Krakow, Poland

d Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397, Marseille, France

e Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260, USA
E-mail: jochena@buffalo.edu

Abstract

The first helicene–NHC–iridium complexes have been prepared in enantiopure forms. Their stereochemical, electronic, and chiroptical features were characterized experimentally and via first-principles calculations, highlighting the helical and iridium-centered chirality.

Graphical abstract: Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

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Article information

DOI
https://doi.org/10.1039/C6CC04257K
Article type
Communication
Submitted
20 May 2016
Accepted
21 Jun 2016
First published
22 Jun 2016

Chem. Commun., 2016,52, 9243-9246

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Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

N. Hellou, C. Jahier-Diallo, O. Baslé, M. Srebro-Hooper, L. Toupet, T. Roisnel, E. Caytan, C. Roussel, N. Vanthuyne, J. Autschbach, M. Mauduit and J. Crassous, Chem. Commun., 2016, 52, 9243 DOI: 10.1039/C6CC04257K

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