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We report the aluminothermic reduction enabled synthesis of silicon hollow microspheres from commercialized silica nanoparticles by controlled transformation and organization. The synergistically integrated merits of a simple process and delicate structural design lay a basis for developing an industrially viable silicon anode with optimized electrochemical performances.

Graphical abstract: Aluminothermic reduction enabled synthesis of silicon hollow microspheres from commercialized silica nanoparticles for superior lithium storage

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